The Anonymous Widower

The Aerosol Tales

When I left Liverpool University in 1968, I was very familiar with the use of products distributed in aerosol cans.

  • I had used aerosol shaving cream, although about that time, I acquired my beard.
  • I certainly used aerosol deodorant, as did most in the 1960s.
  • Aerosol paints were common for covering scuffs and scratches in your car.
  • Aerosols were often used to apply sun protection.
  • Aerosols containing cream or  a non-dairy alternative for culinary use were not unknown.
  • Aweosol lubricants were starting to appear.

Although, I went to work for the chemical giant; ICI, at that time, I had no idea how an aerosol and its can worked.

As ICI at the time, ICI were major manufacturers of aerosol propellants, I quickly learned how they worked.

The Wikipedia entry for Aerosol Spray Dispenser gives a lot of history about aerosol cans and their propellants.

The Wikipedia entry for Propellant has this paragraph describing propellants of the last century.

Chlorofluorocarbons (CFCs) were once often used as propellants, but since the Montreal Protocol came into force in 1989, they have been replaced in nearly every country due to the negative effects CFCs have on Earth’s ozone layer. The most common replacements of CFCs are mixtures of volatile hydrocarbons, typically propane, n-butane and isobutane. Dimethyl ether (DME) and methyl ethyl ether are also used. All these have the disadvantage of being flammable. Nitrous oxide and carbon dioxide are also used as propellants to deliver foodstuffs (for example, whipped cream and cooking spray). Medicinal aerosols such as asthma inhalers use hydrofluoroalkanes (HFA): either HFA 134a (1,1,1,2,-tetrafluoroethane) or HFA 227 (1,1,1,2,3,3,3-heptafluoropropane) or combinations of the two. More recently, liquid hydrofluoroolefin (HFO) propellants have become more widely adopted in aerosol systems due to their relatively low vapor pressure, low global warming potential (GWP), and nonflammability.

Note that the whole range of these chemicals, effect the ozone layer.

Rocksavage Works

ICI’s Rocksavage Works, was an integrated chemical plant by the Mersey,.

  • It made all types of CFCs for aerosols and other purposes.
  • It also made the fire suppressant and extinguisher; Bromochlorodifluoromethane or BCF.
  • Alongside BCF, it made the anaesthetic Halothane or as ICI called it Fluothane.
  • The plant was a poisonous place with all those bromine, chlorine and fluorine compounds.
  • Despite this, the plant had a remarkable safety record.

I had the pleasure of working at the plant and it was where, I had most of my excellent Health and Safety training, from the amazing site foreman; Charlie Akers.

Some of the wisdom he distributed has proved invaluable in aiding my stroke recovery.

I suspect that since the signing of the Montreal Protocol,  the plant has changed greatly or has even been closed.

All that appears to be left is the 800 MW gas-fired Rocksavage power station and a Facebook page.

Aerosol Baked Beans

In those days, I worked most of the time in a lab at Runcorn Heath.

One of the labs near to where I generally worked, in the large research complex, was a lab, where new aerosol products were developed and tested.

One of the standard jokes about that lab, was that they were working on aerosol baked beans. They said, they would develop the product, even of they had to eject them from the can one at a time.

Gift Time

One afternoon, the boss of the aerosol development lab came through with a tray of goodies.

On the tray, which was much like a cinema usherette’s ice cream tray of the sixties was a whole host of partly-labeled aerosol cans. Only clues to what the product might be were written on the outside in felt-tip pen.

I grabbed two, one of which was marked something like lubricating oil and the other was just marked hand cream, which I of course gave to my new wife; C.

We were married for nearly forty years and often, when she bought hand cream, she would remark, that it wasn’t of the same standard as the little can I brought home from work.

It appears to me, that one of the world’s top cosmetic companies and ICI were trying to create the world’s best and probably most expensive hand creams.

DMW

Fast-forward nearly twenty years and I was approached by Lloyds Bank about two individuals, who had developed an aerosol valve, that instead of using CFCs or other ozone-depleting chemicals.

  • By the exploitation of the nether end of fluid dynamics, the propellant of the aerosol was nothing more harmless than pure nitrogen.
  • I formed a company called DMW with the two inventors.
  • John Gummer, who at the time was my MP and Environment Minister, knew of the aerosol valve and he took the details to Montreal.

So did a device developed in Suffolk help push through the Montreal Protocol?

Osbourne Reynolds

I also wonder, if we had some supernatural help. At the time, I lived in the family home of Osbourne Reynolds.

  • He did a lot of the early work on fluid dynamics.
  • He was the first UK Professor of Engineering.
  • He was professor of Engineering at Manchester University for nearly forty years.
  • The Reynolds number is named after him.
  • Remarkably, students are sill taught on the equipment Reynolds designed.
  • Reynolds was certainly one of our great Victorian scientists.

This Wikipedia entry gives more details of his remarkable life and work.

After Montreal the aerosol valve was sold to Johnson & Johnson.

DMW continued to develop other products and we had one, who no-one had any idea about how it worked.

So I discussed it with the Reynolds’s expert at Manchester University and he said he had no idea either.

But he was absolutely certain, that Reynolds would have known.

 

July 17, 2024 Posted by | Food, World | , , , , , , , , , , , , , , , , , , , , | 2 Comments

Should We Stun Animals With Carbon Dioxide?

This post has been prompted by a text from a cardiologist. He said.

Current CO2 crisis reminds me that I think we should be using nitrogen to stun animals before slaughter, not CO2.

I heard a project on Farming Today a few months ago about CO2 stunning and thought it a great mistake as it can stimulate breathing and cause distress in some.

Have you seen anything on using nitrogen?

I haven’t but I must admit, I’ve had the thought myself and have also asked myself, if the gas in food packages is nitrogen, which would be logical to me.

I do have some thoughts.

The Best Beef I Ever Tasted

Over forty years ago, I used to buy beef from a local farmer in Suffolk.

  • It would now be considered organic.
  • All the farmer’s animals got the best care.
  • He used to slaughter the animals himself in the field after giving them a pick of grass, using a captive bolt.

It was certainly, the best beef, I’ve ever tasted. But then the animals suffered no distress.

Medical Uses Of Carbon Dioxide

This is from the Wikipedia entry for carbon dioxide.

In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the O2/CO2 balance in blood.

This would appear to support the cardiologist’s text.

Is Carbon Dioxide Cheaper Than Nitrogen?

I have found these prices for ten litre cylinder of both gases.

  • Carbon Dioxide – £78
  • Nitrogen – £54

On this quick comparison, there would appear to not be a large difference.

Availability Of Nitrogen

Reading the Wikipedia entry for nitrogen, it appears to me, that production of oxygen-free nitrogen is not that difficult and this may explain the price comparison with carbon dioxide.

Nitrogen And The Death Penalty In The United States

This is a section called Euthanasia in the Wikipedia entry for nitrogen.

Nitrogen gas has become the inert gas of choice for inert gas asphyxiation, and is under consideration as a replacement for lethal injection in Oklahoma.

As nitrogen is an asphyxiant gas, some jurisdictions have considered inert gas asphyxiation by inhalation of pure nitrogen as a means of capital punishment (as a substitute for lethal injection).

I have been totally against the death penalty since meeting Jimmy O’Connor in the 1970s.

Conclusion

It strikes me that nitrogen could be used to stun animals as a more humane alternative to carbon dioxide.

September 24, 2021 Posted by | Food | , , , | 4 Comments