CO2 to SAF: A One-Step Solution
The title of this post is the same as that of this article on the Chemical Engineer.
This is the sub-heading,
Oxford spinout OXCCU has launched a demonstration plant at London Oxford Airport to trial its one-step process of turning CO2 into sustainable aviation fuel (SAF). Aniqah Majid visited the plant to investigate the benefits of its “novel” catalyst
One word in this sub-heading caught my eye.
When I was a young engineer in the Computer Techniques section in the Engineering Department at ICI Plastics Division, I did a small mathematical modelling project for this chemical engineer, using the section’s PACE 231-R analogue computer.
He was impressed and gave the 23-year-old self some advice. “You should apply that beast to catalysts.”
I have never had the chance to do any mathematically modelling of catalysts either at ICI Plastics or since, but I have invested small amounts of my own money in companies working with advanced catalysts.
So when OXCCU was picked up by one of my Google Alerts, I investigated.
I like what I found.
The three raw ingredients are.
- Green Hydrogen
- Carbon dioxide perhaps captured from a large gas-fired powerstation like those in the cluster at Keadby.
- OXCCU’s ‘novel’ catalyst, which appears to be an iron-based catalyst containing manganese, potassium, and organic fuel compounds.
I also suspect, that the process needs a fair bit of energy. These processes always seem to, in my experience.
This paragraph outlines how sustainable aviation fuel or (SAF) is created directly.
This catalyst reduces CO2 and H2 into CO and H2 via a reverse water gas shift (RWGS) process, and then subsequently turns it into jet fuel and water via Fischer-Tropsch (FT).
The Wikipedia entry for Fischer-Tropsch process has this first paragraph.
The Fischer–Tropsch process (FT) is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of 150–300 °C (302–572 °F) and pressures of one to several tens of atmospheres. The Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons.
Note.
- I wouldn’t be surprised that to obtain the carbon monoxide and hydrogen or syngas for the Fischer-Tropsch process, excess hydrogen is used, so the OXCCU process may need a lot of affordable hydrogen, some of which will be converted to water in the RWGS process.
- The high temperatures and pressures for the Fischer-Tropsch process will need a lot of energy, as I predicted earlier.
But I don’t see why it won’t work with the right catalyst.
The Wikipedia entry for the Fischer-Tropsch process also says this.
Fischer–Tropsch process is discussed as a step of producing carbon-neutral liquid hydrocarbon fuels from CO2 and hydrogen.
Three references are given, but none seem to relate to OXCCU.
OXCCU have a web site, with this title.
Jet Fuel From Waste Carbon
And this mission statement underneath.
OXCCU’s mission is to develop the world’s lowest cost, lowest emission pathways to make SAF from waste carbon, enabling people to continue to fly and use hydrocarbon products but with a reduced climate impact.
It looks like they intend to boldly go.
Conclusion
My 23-year-old self may have been given some good advice.
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