Air Liquide Paves The Way For Ammonia Conversion Into Hydrogen With New Cracking Technology
The title of this post, is the same as that of this article on Hydrogen Central.
These two paragraphs outline the story.
Air Liquide announces the construction of an industrial scale ammonia (NH3) cracking pilot plant in the port of Antwerp, Belgium. When transformed into ammonia, hydrogen can be easily transported over long distances. Using innovative technology, this plant will make it possible to convert, with an optimized carbon footprint, ammonia into hydrogen (H2).
With this cracking technology, Air Liquide will further contribute to the development of hydrogen as a key enabler of the energy transition.
I think this could be very significant, in the development of hydrogen as an industrial fuel for heavy energy users.
Hydrogen Fuel Pioneer Wins £247k Funding For Carbon Capture Tech
The title of this post, is the same as that of this article on gasworld.
This is the introductory paragraph.
UK-based waste-to-hydrogen specialist Compact Syngas Solutions (CSS) has won £246,568 from the Hydrogen BECCS (bioenergy with carbon capture and storage) Innovation Programme.
I first wrote about Compact Syngas Solutions, in Welsh Firm Wins £300K BEIS Grant To Advance Hydrogen Fuel Tech.
Compact Syngas Solutions appear to be developing a process to turn waste, that would otherwise go to landfill, into green hydrogen.
- The first stage turns the waste into syngas using gasification.
- This process produces carbon dioxide, which must be captured.
- Compact Syngas Solutions seem to have found a chemical mechanism, that uses water to capture this carbon dioxide instead of ammonia-derived amines.
The last two paragraphs of the article state Compact Syngas Solutions’s plans.
Intended to be portable, CSS plans to develop ten Micro H2 hubs complete with four gasifiers.
Capable of producing 60kg of hydrogen and capturing 3.1kg of CO2 per day, the technology could contribute to full-scale Waste-to-Syngas-Liquid-Fuel facilities, leading to a 50,100 tonne CO2 capture capacity in the UK.
I feel, that if this technology can be made to work at scale, then Compact Syngas Solutions will have a viable way to make green hydrogen.
ITM Power’s 24MW Electrolyser Sale to Yara
The title of this post, is the similar to that of this press release from ITM Power. I just added a few words.
These are the first three paragraphs.
ITM Power (AIM: ITM), the energy storage and clean fuel company, is pleased to provide details of the sale of a 24MW electrolyser to Linde Engineering contained in the Company’s Half Year Report issued yesterday. The electrolyser is to be installed at a site operated by Yara Norge AS (“Yara”) located at Herøya outside Porsgrunn, about 140 km southwest of Oslo. The site covers an area of approximately 1.5 square kilometres and is the largest industrial site in Norway. The Porsgrunn site produces 3 million tons of fertiliser per year.
The hydrogen required for ammonia production is currently produced from SMR. Yara intends to start replacing this grey hydrogen with green hydrogen produced from renewable energy and electrolysis. The 24MW system supplying 10,368 kg/day of hydrogen will account for approximately 5% of the plant’s consumption and serve as a feasibility study for future upscaling. Yara has received a grant of up to NOK 283m (£23.6m,pending ESA approval) from Enova SF, a Government funding body, to invest in green solutions for hydrogen used for industrial purposes in Norway.
The electrolyser equipment is due to be ready for shipment from ITM Power in Q4 2022 with revenue realised in the Company’s 2022/2023 financial year.
These are my thoughts.
The Size Of The Electrolyser
A 24 MW electrolyser, that produces 10,368 Kg of hydrogen/day may sound a large device.
This is an extract from the press release.
In January 2021, the Company received an order for the world’s then largest PEM electrolyser of 24MW from Linde. In October 2021, the Company, with Linde, announced the deployment of a 100MW electrolyser at Shell’s Rhineland refinery, following the start-up of an initial 10MW facility at the site.
It appears that ITM Power have built one before and one four times the size has been ordered.
What Size Of Electrolyser Would Yara Need To Fully Decarbonise Ammonia Production?
According to the press release, a 24 MW electrolyser will produce five percent of the plant’s consumption, which means that a 480 MW electrolyser will be needed, if Yara use an ITM electrolyser to produce all their hydrogen.
Will manufacture of an electrolyser of this size be a problem for ITM Power?
The press release says this about electrolyser production.
ITM Power operates from the world’s largest electrolyser factory in Sheffield with a capacity of 1GW (1,000MW) per annum, with the announced intention to build a second UK Gigafactory in Sheffield with a capacity of 1.5GW expected to be fully operational by the end of 2023. The Group’s first international facility, expected to have a capacity of 2.5GW per annum, is intended to be operational by the end of 2024, bringing total Group capacity to 5GW per annum.
It also says that the company has raised £250m to accelerate expansion.
The Delivery Date
The delivery date of the electrolyser is stated as Q4 2022.
I find this rather quick, which makes me believe that one of the reasons for the success of ITM Power is their production process.
How Much Ammonia Is Produced Worldwide?
This is an extract from this publication from the Royal Society, which is entitled Ammonia: Zero-Carbon Fertiliser, Fuel And Energy Store.
Current global ammonia production is about 176 million tonnes per year and is predominantly achieved through the steam reforming of methane to produce hydrogen to feed into ammonia synthesis via the Haber Bosch process.
Ammonia production is a highly energy intensive process consuming around 1.8% of global energy output each year (steam methane reforming accounts for over 80% of the energy required) and producing as a result about 500 million tonnes of carbon dioxide (about 1.8% of global carbon dioxide emissions)2,3,4. Ammonia synthesis is significantly the largest carbon dioxide emitting chemical industry process. Along with cement, steel and ethylene production, it is one of the ‘big four’ industrial processes where a decarbonisation plan must be developed and implemented to meet the netzero carbon emissions target by 2050.
It looks like Linde and ITM Power have a fairly simple plan to decarbonise world ammonia production. And they have started with one of the easier targets; Yara in the very environmentally-correct Norway.
I estimate that to produce 176 million tonnes of green ammonia will need over 28 GW of electrolyser capacity.
Conclusion
If Linde and ITM Power can persuade the world, that their technology is the way to go, then they’ve got it made.
Green Ships Ahoy Along Vital Corridors
The title of this post, is the same as that of this article on 7 News Australia.
These are the first two paragraphs.
Australia’s biggest miners are preparing for a day of reckoning.
Shipping accounts for two to three per cent of global greenhouse gas emissions so manufacturers and retailers are no longer just considering what appears in national targets.
The article then goes on to explain how the big mining companies are cutting their emissions.
This paragraph illustrates how important mining and shipping is to Australia.
Resources and energy earnings passed $300 billion for the first time in 2020-21 and will surge towards $400 billion in 2021-22, according to December figures.
Hence the big need for ships fuelled by lower carbon fuels.
Grand Central DMU To Be Used For Dual-Fuel Trial
The title of this post, is the same as that of this article on Railway Gazette.
This is the first two paragraphs.
An Alstom Class 180 Adelante diesel-hydraulic multiple-unit is to be converted to run on a combination of diesel and liquefied natural gas in a dual-fuel technology demonstration project.
One car of the DMU which Arriva-owned open access inter-city operator Grand Central leases from Angel Trains is to be equipped with dual-fuel technology company G-volution’s Optimiser system, which is used in the road sector. The modifications are expected to be straightforward, enabling trials on the national network to start later this year.
The article dates from May 2019 and I suspect the small matter of the pandemic and Grand Central’s resulting three closures due to lockdowns are the reason this development hasn’t been heard of since.
But this was the London end of the Class 180 train, that I rode from Mirfield to King’s Cross.
I haven’t ridden in a Class 180 train for some years and there was nothing to indicate from the performance, that it was not a standard train.
There are fourteen of these 125 mph trains.
This explanatory video of G-volution’s technology is on the G-volution web site.
Note that in the video, one of G-volution’s Managing Director; Chris Smith says that the technology is fuel agnostic and will work with a range of fuels including ammonia, biodiesel, bio-LPG, hydrogen and methanol.
Conclusion
It will be very interesting to see what is decided to be the ideal fuel-combination and how much reduction is possible for the various emissions.
I’ll end with two questions.
Will Passengers Like The New Trains?
What is there not to like! Same train and performance with lower emissions.
Will Cummins Like What G-volution Have Done To Their Engines?
Cummins might be a bit miffed, as they built the QSK19 engines for the Class 180 trains and may have their own plans for them. But they are a practical and flexible company in my experience and generally they do what the customer needs or wants. Decarbonisation is surely in everybody’s interest.
Incidentally, the same Cummins diesel engines are used in the TransPennine Express, Class 185 trains, I’ve been riding in most of today.
There are fifty-one of these 100 mph trains in use in the UK. They could be ideal for some long routes, if they could be converted to low-emission.
KEPSA Signs Large-Scale Green Energy Projects MoU In Kenya
The title of this post, is the same as that of this article on ESI Africa.
This is the first paragraph.
The Kenya Private Sector Alliance (KEPSA) has signed a Memorandum of Understanding (MoU) with green energy company Fortescue Future Industries (FFI) to help facilitate its members participation in new large scale green energy projects in Kenya.
FFI are planning a possible green hydrogen and green ammonia facility in the country, that will use renewable energy.
Andrew Forrest is building up the air miles again.
Fortescue Future Industries To Convert Ship To Ammonia-Fuelled Propulsion Next Year
The title of this post is the same as that of this article on Ship and Bunker.
Andrew Forrest is at it again.
Namibia Is Building A Reputation For The Cheapest Green Hydrogen
The title of this post, is the same as that of this article on Hydrogen Fuel News.
This paragraph explains the deal that Germany and Namibia have done.
Germany, the largest economy in Europe, has just closed a partnership with Namibia, for a supply of the cheapest green hydrogen. The Southern African country is aiming to produce its H2, made with renewable energy, for prices as low as $1.8/kg. The European nation intends to import massive volumes of what it believes will be the most affordable renewable H2 in the world. It has signed a deal with Namibia that steps up the worldwide scramble to secure the best options for H2 supply connected with substantial renewable installations.
Note.
- Namibia has the ability to produce large amounts of solar and wind energy.
- I suspect the hydrogen will be converted to liquid ammonia for shipment to Germany.
The Gremans are building a large hydrogen terminal at Wilhelmshaven, which I wrote about in Uniper To Make Wilhelmshaven German Hub For Green Hydrogen; Green Ammonia Import Terminal.
Although, Namibia has now been an independent country since 1990, from 1884 to 1915 it was the German colony of German South West Africa.
Hopefully, this deal will work out to the benefit of both Germany and Namibia.
Hydrogen And The Anglo-Australian Trade Deal
This article on the BBC is entitled UK And Australia In First Post-Brexit Trade Deal.
I can see one very profitable result of this trade deal.
The world has a large and growing need for green hydrogen produced by renewable energy.
Australia is embracing the hydrogen economy and I have posted about Australia hydrogen developments several times.
This post is entitled H2U Eyre Peninsula Gateway Hydrogen Project Begins Largest Green Ammonia Plant and it describes how Australia will convert renewable electricity into liquid green ammonia for export to Japan.
Australia has a lot of sun and can create a lot of green hydrogen and ammonia for South East Asia.
Electrolysers need to be used to convert solar and wind electricity into hydrogen, which would be exported in tankers either as liquid hydrogen or liquid ammonia.
The largest hydrogen electrolyser factory in the world, is owned by ITM Power and is located in Sheffield/Rotherham. It has a capacity to build 1 GW of electrolysers in a year.
Looking at the electrolyser market, I can see the company needing another similar-sized factory.
Australia’s Solar Power Potential
This section in the Wikipedia entry for Solar Power In Australia is called Potential.
These are some points from the section.
- Typically, in the winter months, a square metre of much of Australia receives 4 kWh of insolation per day.
- Some areas in the North receive fifty percent more.
- Australia has the potential to install 179 GW of solar power on roofs across the nation.
Australia used to curse the sun because of all the cancer it brought. Now it could make them the world’s hydrogen powerhouse!
At present ninety percent of Australia’s solar panels are made in China.
But that may not be for ever, if what I wrote in Solar To Hydrogen Efficiency Record Broken By Australian National University Researchers, turns out to lead to an alternative technology to create hydrogen.
An Anglo-Australian Hydrogen Alliance
What better possible place to build a second electrolyser factory is there, than in Australia?
- The Australian economy can use a lot of hydrogen for transport.
- Australia is embracing hydrogen technology.
- Australia is well-placed to export electrolysers to their friends in South East Asia.
- Australia has the sun to produce massive amounts of green hydrogen.
If the UK and Australia developed hydrogen together, it would be good for both countries.
- Australia can develop massive levels of renewable electricity from solar.
- The UK can develop massive levels of renewable electricity from wind and possibly other sources.
- Both countries are researching the ways to create and use hydrogen.
- Both countries could produce hydrogen for nearby economies needing large amounts of hydrogen.
- Many UK and Australian companies operate in both countries.
But above all, we haven’t had a major fall-out with Australia since the Bodyline Tour in 1932-1933.
Could West Africa Become A Green Energy Powerhouse?
I ask this question, because I have just read this article on Hydrogen Fuel News, which is entitled Green Hydrogen Potential Causes Germany to court West African countries.
The article has this sub-title.
Nations in that part of Africa have the capacity to meet 1500 times Germany’s 2030 H2 demand.
That would appear to be a massive amount of hydrogen.
This extract from the article, talks about energy production.
Initial results for the 15 West African Economic Area (ECOAS) countries revealed that a massive three quarters of West African land is appropriate for wind turbines. Moreover, the electricity production from wind energy in the region costs about half the amount it would in Germany.
Additionally, solar power systems can also be economically operated on about one third of the West African region.
Add in a few large electrolysers and you have the hydrogen.
The hydrogen can be transported to Germany by tanker, either as hydrogen or ammonia.
The German strategy is to be underpinned by education, as this extract explains.
In support of developing West African green hydrogen production, a new master’s graduate program on clean H2 technology will begin in September. The purpose of the program will be to train local green hydrogen scientific specialists. The first three waves of the program are expected to train about 180 students attending four universities in Côte d’Ivoire, Togo, Senegal, and Niger.
Perhaps the Commonwealth should do something similar in West African countries like Gambia, Ghana, Nigeria and Sierra Leone.
After all many parts of Australia have very similar climate and population densities and probably energy generation potential to large parts of West Africa.
The Geographical Advantage
It should also be noted that geographically West Africa is close to Europe by ship.
There are no pinch points like the Suez Canal
As the European hydrogen gas network grows, the journey will get shorter.
Does anybody know how long it would take a tanker to go between say Accra in Ghana to Rotterdam?
Conclusion
I would see four main benefits coming to West Africa.
- Electricity for all.
- Employment to support the new industries.
- Hydrogen to power transport.
- The value of all those exports.
Hopefully, the standard of living of all those in West Africa would improve.
The Anonymous Widower 